2006
Towards molecular electronics with large-area molecular junctions
Hylke B. Akkerman1, Paul W. M. Blom1, Dago M. de Leeuw2 & Bert de Boer
nature04699
supporting information
2007
Ultrathin p-Conjugated Polymer Films for Simple Fabrication of Large-Area Molecular Junctions
Federico Milani,[a] Christian Grave,[a] Violetta Ferri,[a] Paolo Samorì,[b] and Maria Anita Rampi
ChemPhysChem 2007, 8, 515 – 518
ポリマー（ドープしてない）をSAM上にコートして、水銀コンタクト。
Electron tunneling through alkanedithiolself-assembled monolayers in large-area molecular junctions
Hylke B. Akkerman†, Ronald C. G. Naber†, Bert Jongbloed†, Paul A. van Hal‡, Paul W. M. Blom†, Dago M. de Leeuw†‡, and Bert de Boer
PNAS-2007-Akkerman-11161-6
2008
Upscaling, integration and electrical characterization of molecular junctions
PAUL A. VAN HAL1, EDSGER C. P. SMITS1,2,3, TOM C. T. GEUNS1, HYLKE B. AKKERMAN2,
BIANCA C. DE BRITO1, STEFANO PERISSINOTTO4, GUGLIELMO LANZANI4, AUKE J. KRONEMEIJER2, VICTOR GESKIN5, JE ́ ROˆ ME CORNIL5, PAUL W. M. BLOM2, BERT DE BOER2 AND DAGO M. DE LEEUW
nnano.2008.305
supporting information
集積化
Robust reproducible large-area molecular rectifier junctions
Hui-Juan Che,1,2 Perq-Jon Chia,1,a Lay-Lay Chua,1 Sankaran Sivaramakrishnan,1 Jie-Cong Tang,2 Andrew T. S. Wee,1 Hardy S. O. Chan,2,b and Peter K. H. Ho
APPLIED PHYSICS LETTERS 92, 253503 2008
Self-Assembled-Monolayer Formation of Long Alkanedithiols in Molecular Junctions
Hylke B. Akkerman, Auke J. Kronemeijer, Paul A. van Hal, Dago M. de Leeuw, Paul W. M. Blom, and Bert de Boer
small 2008, 4, No. 1, 100 – 104
修飾濃度依存性など
Reversible Conductance Switching in Molecular Devices
Auke J. Kronemeijer, Hylke B. Akkerman, Tibor Kudernac, Bart J. van Wees, Ben L. Feringa, Paul W. M. Blom, and Bert de Boer
Adv. Mater. 2008, 20, 1467–1473
フォトクロミック分子のコンダクタンスススイッチング。上電極は金だが、光応答しているらしい。可逆。
2009
Electrical conduction through self-assembled monolayers in molecular junctions: Au/ molecules/Au versus Au/molecule/PEDOT:PSS/Au
Gunuk Wang, Hana Yoo, Seok-In Na, Tae-Wook Kim, Byungjin Cho, Dong-Yu Kim, Takhee Lee
Thin Solid Films 518 (2009) 824–828
PEDOT/PSSありと無しでデバイスの収率とβなどを比較。PEDOT/PSSありのほうが良いといっている。
Molecular Monolayer Nonvolatile Memory with Tunable Molecules
Junghyun Lee, Hojong Chang, Sangkwan Kim, Gyeong Sook Bang, and Hyoyoung Lee
8501_ftp
Ru錯体で非常に弱いヒステリシスループを利用
2010
Stability of large-area molecular junctions
Hylke B. Akkerman a, Auke J. Kronemeijer a, Jan Harkema a, Paul A. van Hal b, Edsger C.P. Smits a,b, Dago M. de Leeuw a,b,*, Paul W.M. Blom
Organic Electronics 11 (2010) 146–149
大気中で888日安定。
50℃くらいでダメージを受ける。
Vertically Stacked Molecular Junctions: Toward a Three-Dimensional Multifunctional Molecular Circuit
Elad D. Mentovich,†,‡ Itsik Kalifa,‡ Natalie Shraga,† Grergory Avrushchenko,‡ Michael Gozin,† and Shachar Richter
jz100373y-vertially stacked device
縦型スタック。タンパク使用。
Electrical characteristics of conjugated self-assembled monolayers in large-area molecular junctions
A. J. Kronemeijer, E. H. Huisman, H. B. Akkerman, A. M. Goossens, I. Katsouras, P. A. van Hal, T. C. T. Geuns, S. J. van der Molen, P. W. M. Blom, and D. M. de Leeuw
Applied Physics Letters 97, 173302 (2010); doi: 10.1063/1.3503607
Universal Scaling in Highly Doped Conducting Polymer Films
A. J. Kronemeijer,1 E. H. Huisman,1 I. Katsouras,1 P. A. van Hal,2 T. C. T. Geuns,2 P. W. M. Blom,1,3 S. J. van der Molen,4 and D. M. de Leeuw
PhysRevLett.105.156604
PEDOT/PSS薄膜層の特性
2011
A New Approach for Molecular Electronic Junctions with a Multilayer Graphene Electrode
Gunuk Wang, Yonghun Kim, Minhyeok Choe, Tae-Wook Kim, and Takhee Lee
755_ftp
トップ電極にグラフェン層を使用
Extending the voltage window in the characterization of electrical transport
of large-area molecular junctions
Ilias Katsouras,1,a) Auke J. Kronemeijer,1,2 Edsger C. P. Smits,3 Paul A. van Hal,4 Tom C. T. Geuns,4 Paul W. M. Blom,1,3 and Dago M. de Leeuw
Applied Physics Letters 99, 013303 (2011); doi: 10.1063/1.3608154
パルスバイアス印可で耐電圧向上。IVはexponentialではなく、power law。
Electrical transport characteristics through molecular layers
Gunuk Wang,a Tae-Wook Kimb and Takhee Lee
c1jm12702k
膜系を中心にしたReview
Universal Scaling of the Charge Transport in Large-Area Molecular Junctions
Auke J. Kronemeijer, Ilias Katsouras, Eek H. Huisman, Paul A. van Hal, Tom C. T. Geuns, Paul W. M. Blom, and Dago M. de Leeuw*
1593_ftp
IVカーブのスケーリング則がPEDOT/PSSだけの薄膜の時（2010 Universal Scaling in Highly Doped Conducting Polymer Films）とよく似ている。単分子の特性が本当に出ているのかに疑問を呈する論文
2012
Organic field-effect transistors as a test-bed for molecular electronics: A combined study with large-area molecular junctions
Kamal Asadi a,⇑, Ilias Katsouras b, Jan Harkema b, Fatemeh Gholamrezaie a,b, Edsger C.P. Smits c, Fabio Biscarini d, Paul W.M. Blom b,c, Dago M. de Leeuw
Organic Electronics 13 (2012) 2502–2507
有機薄膜FETの電極部分にSAMを生やしたときの接触抵抗をはかる、という位置づけ。
Organic field-effect transistors as new paradigm for large-area molecular junctions
Stefano Casalini a,⇑, Arian Shehu a, Silvia Destri b, William Porzio b, Maria Cecilia Pasini b, Francesco Vignali b, Francesco Borgatti a, Cristiano Albonetti a, Francesca Leonardi c,a, Fabio Biscarini
Organic Electronics 13 (2012) 789–795
Applying Large-Area Molecular Technology to Improve Magnetoresistive Performance of Hybrid Molecular Spin Valves
Jung-Chi Tai1, Jang-Chang Huang1, Yin-Ming Chang1, Kai-Shin Li1, Wen-Chung Chiang2, and Minn-Tsong Lin
078-APEX-5-063006-2012-Applying Large-Area Molecular Technology to Improve Magnetoresistive Performance
Molecular Junctions of Self-Assembled Monolayers with Conducting Polymer Contacts
Alexander B. Neuhausen, Ali Hosseini, Joseph A. Sulpizio, Christopher E. D. Chidsey, and David Goldhaber-Gordon
neuhausen-acsnano-2012
ナノスケールの穴ぼこでやりました。絶縁層には40nmのシリコンナイトライドを使用。フォトレジストのマイクロポアの場合は、濡れ性が問題になりやすいのに対して、この方法だとどんな単分子膜でもOK。これまでに行われたPEDPOT/PSS側の工夫についてもまとめてある。
Long-Range Electron Transport of Ruthenium-Centered Multilayer Films
via a Stepping-Stone Mechanism
Kei-ichi Terada,†, Hisao Nakamura,‡ Katsuhiko Kanaizuka,§,^ Masa-aki Haga,§ Yoshihiro Asai,‡,* and
Takao Ishida
nn300126m
βの測定に使用。確か、酸化チタンバリア。
2013
Voltage-Controlled Nonvolatile Molecular Memory of an Azobenzene Monolayer through Solution-Processed Reduced Graphene Oxide Contacts
Misook Min, Sohyeon Seo,* Sae Mi Lee, and Hyoyoung Lee
Adv. Mater. 2013, 25, 7045–7050
グラフェン使用